Know Your Users
Although some people bristle at the term "users" (perhaps due to
some system administrators' use of the term in a derogatory manner), it
is used here with no such meaning implied. Users are simply those
people that use the systems and resources for which you are
responsible. As such, they are central to your ability to successfully
administer your systems; without understanding your users, how can you
understand the system resources they will require?
For example, consider a bank teller. A bank teller will use a
strictly-defined set of applications, and requires little in the way of
system resources. A software engineer, on the other hand, may use many
different applications, and will always welcome more system resources
(for faster build times). Two entirely different users with two
entirely different needs.
Make sure you learn as much about your users as you can.